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Titanium dioxide occurs in nature as well-known minerals rutile, anatase and brookite, and additionally as two high pressure forms, a monoclinic baddeleyite-like form and an orthorhombic α-PbO2-like form, both found recently at the Ries crater in Bavaria.[1][2] The most common form is rutile,[3] which is also the equilibrium phase at all temperatures.[4] The metastable anatase and brookite phases both convert to rutile upon heating.[3][5] Rutile, anatase and brookite all contain six coordinated titanium.
Titanium dioxide has eight modifications – in addition to rutile, anatase and brookite there are three metastable forms produced synthetically (monoclinic, tetragonal and orthorombic), and five high pressure forms (α-PbO2-like, baddeleyite-like and cotunnite-like):
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